I am afraid, the limit of 99 items per question is fixed. However, there are two other ways you may want to go.
1) You may try the "Visual Placements" question type, calculating the emotions from the X-Y-coordinates will be no challange.
2) You may want to create the question by using JavaScript and just store the result to SoSci Survey, using an internal variable.
3) If you take a look into the source code of the page with "SVG as selection", you'll see that all the options are just added by ....registerMarker(...)
. You could just add more JavaScript code to circumvent the 99 items limit.
to my understanding the Element-IDs are assigned randomly.
It is your SVG editor which creates the IDs. Some editors like Inkscape allow editing the names at will.